Zur Synthese der Carbäthoxyalkyl??phosphine
K Issleib, G Thomas
Index: Issleib,K.; Thomas,G. Chemische Berichte, 1961 , vol. 94, p. 2244 - 2251
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Citation Number: 25
Abstract
Abstract Sek. aliphatische und cycloaliphatische Phosphine reagieren mit Halogen- carbonsäure-äthylestern unter Bildung quartärer Phosphoniumsalze des Typs [R 2 P (H)[BOND] CH 2· CO 2 C 2 H 5] Hal, aus denen mittels NaOH bzw. NaOC 2 H 5 die entsprechenden Carbäthoxyalkyl-phosphine zugänglich sind.—Aus (C 6 H 5) 2 PH und BrCH 2· CO 2 C 2 H 5 kann auch bei gleichzeitiger Abspaltung von HBr das Biscarb- ...
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