Highly regioselective hydroselenation and double-bond isomerization of terminal alkynes with benzeneselenol catalyzed by bis (triphenylphosphine) palladium (II) …

…, M Kotani, H Kusano, A Nomoto, A Ogawa

Index: Ozaki, Toshiya; Kotani, Mao; Kusano, Hiroki; Nomoto, Akihiro; Ogawa, Akiya Journal of Organometallic Chemistry, 2011 , vol. 696, # 1 p. 450 - 455

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Citation Number: 11

Abstract

Transition-metal-catalyzed addition reactions of heteroatom compounds bearing a heteroatom-hydrogen linkage to carbon–carbon unsaturated bonds are very useful in terms of highly regio- and stereoselective synthesis of heteroatom compounds as well as excellent atom economy [1], 1a, 1b, 1c and 1d. Indeed, transition-metal-catalyzed hydroboration, hydrosilylation, hydrostannation, hydrophosphination, and hydrothiolation are widely ...