Sugar Esters. II. 1 The Structure of the Alkali-Stable Phosphate Esters Obtained in Alkali Treatment of Sugar Diphosphates and Cyclic Phosphates
JB Lee
Index: Lee,J.B. Journal of Organic Chemistry, 1963 , vol. 28, p. 2473 - 2475
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Citation Number: 4
Abstract
The alkali-lability of certain phosphate esters, 2a in particular those of some carbohydrates,* b contrasts sharply with the stability of most alkyl phosphate^.^ Unlike lability in carbohydrate sulfonates, phosphate ester-lability does not involve anhydro compound formation; in many ways a closer parallel is shown with 0-alkyl-and 0-a1 kylidenehexoses. These points have been reviewed recently and mechanisms discussed. Only preliminary ...
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