Stemodin synthesis (II)—highly diastereoselective formal total synthesis of−-stemodin via Pd 2+-promoted cycloalkenylation reaction
M Toyota, T Seishi, K Fukumoto
Index: Toyota, Masahiro; Seishi, Takashi; Fukumoto, Keiichiro Tetrahedron, 1994 , vol. 50, # 12 p. 3673 - 3686
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Citation Number: 18
Abstract
Diastereoface-selective Pd2+-promoted cycloalkenylation reaction (22→ 24) has been employed as the key step for a conceptually new and highly diastereocontrolled formal total synthesis of−-stemodin (1). Interestingly, the synthetic intermediates (12) and its ...
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