Highly selective biaryl formation by the cyclooligomerization of arylethynes catalyzed by rhodium and ruthenium porphyrins

P Tagliatesta, E Elakkari, A Leoni, A Lembo…

Index: Tagliatesta, Pietro; Elakkari, Elfituri; Leoni, Alessandro; Lembo, Angelo; Cicero, Daniel New Journal of Chemistry, 2008 , vol. 32, # 11 p. 1847 - 1849

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Citation Number: 11

Abstract

Rhodium and ruthenium porphyrins catalyze the one-pot formation of biaryl derivatives from arylethynes with high selectivity, giving interesting derivatives not easy to obtain using other different methods; the porphyrin catalysts can be recovered and reused after several experiments with no change of activity.

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