Nucleophilic aromatic substitution reactions of unactivated aryl halides with thiolate ions in hexamethylphosphoramide

P Cogolli, F Maiolo, L Testaferri, M Tingoli…

Index: Cogolli,P. et al. Journal of Organic Chemistry, 1979 , vol. 44, # 15 p. 2642 - 2646

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Citation Number: 93

Abstract

Discussion The results of competitive experiments collected in Table I indicate that the four unsubstituted halogenobenzenes do not present substantial differences in reactivity toward the isopropanethiol anion in HMPA; the observed halogen mobility sequence is I> F> Br> C1.