Studies of exchange equilibria of palladium (II) tertiary phosphine complexes

WJ Louch, DR Eaton

Index: Louch, W. J.; Eaton, D. R. Inorganica Chimica Acta, 1978 , vol. 30, p. 243 - 250

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Citation Number: 10

Abstract

Abstract The reactions of tertiary phosphine complexes of Pd (II) with phosphine! igand: have been investigated by NMR and conductivity measurements. Depending on the nature of the phosphine ligand either ligand exchange or the formation of cationic complexes can occur. Relative equilibrium constants for these reactions have been obtained. NMR line broadening experiments have enabled the relative rates of ligand exchange between the ...