Highly selective monotetrahydropyranylation of symmetrical diols catalysed by a strongly acidic ion-exchange resin

T Nishiguchi, M Kuroda, M Saitoh, A Nishida…

Index: Nishiguchi, Takeshi; Kuroda, Masahumi; Saitoh, Masahiko; Nishida, Akiko; Fujisaki, Shizuo Journal of the Chemical Society, Chemical Communications, 1995 , # 24 p. 2491 - 2492

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Citation Number: 10

Abstract

Several primary and secondary symmetrical diols, ranging from propane-1, 3-diol to decane- 1, 10-diol, are selectively monoprotected by monotetrahydropyranyl ether formation catalysed by a strongly acidic ion-exchange resin (Dowex 50w× 2, 50–100 mesh) in a 3, 4- dihydro-2H-pyran-hydrocarbon mixture.

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