Reduction of 1-substituted 7-chloro-7-fluoronorcaranes with tributyltin hydride
…, T Ishihara, E Ohtani, H Sawada
Index: Ando, Teiichi; Ishihara, Takashi; Ohtani, Eiichi; Sawada, Hiroki Journal of Organic Chemistry, 1981 , vol. 46, # 22 p. 4446 - 4450
Full Text: HTML
Citation Number: 0
Abstract
The stereospecificity of the reduction of 1-fluoro-(l), 1-methoxy-(2), 1-(methoxycarbony1)-(3), 1-(trimethylsily1)-(4), 1-methyl-(5), and 1-unsubstituted 7-chloro-7-fluoronorcarane (6) with neat tributyltin hydride has been measured and found to decrease in the order 5= 4> 6> 3> 2> 1. This suggests that the configurational stability of the 7-fluoro-7-norcaryl radical is affected by the substituent situated at the position 8 to the radical center; the 8- ...
Related Articles:
[Tojo, Masahiro; Fukuoka, Shinsuke; Tsukube, Hiroshi Journal of Molecular Catalysis A: Chemical, 2011 , vol. 337, # 1-2 p. 89 - 94]
Dehydrohalogenations of cis-and trans-1-bromo-2-flourocyclohexanes
[Hudlicky,H. Journal of Fluorine Chemistry, 1986 , vol. 32, p. 441]
[Tojo, Masahiro; Fukuoka, Shinsuke; Tsukube, Hiroshi Bulletin of the Chemical Society of Japan, 2011 , vol. 84, # 3 p. 333 - 340]
[Tojo, Masahiro; Fukuoka, Shinsuke; Tsukube, Hiroshi Bulletin of the Chemical Society of Japan, 2011 , vol. 84, # 3 p. 333 - 340]