Photoaddition of alcohols to some 1, 2, 3, 6-tetrahydropyridines

…, M Šputová, P Trška, D Vaculíková…

Index: Silhankova, Alexandra; Davidova, Dagmar; Sputova, Michaela; Trska, Petr; Vaculikova, Dana; et al. Collection of Czechoslovak Chemical Communications, 1987 , vol. 52, # 5 p. 1298 - 1304

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Abstract

Abstract Photochemical addition of methanol to 1, 2, 3, 6-tetrahydropyridine derivatives Ia, Ib, Id-Ii and III afforded methoxypiperidines IIa-IIg and IV as Markovnikov type addition products. Reduction of 4-methyl-1-(2-propenyl) pyridinium bromide with sodium borohydride yielded 4-methyl-1-(2-propenyl)-1, 2, 3, 6-tetrahydropyridine (Ig).