Precise Control of Intramolecular Charge??Transport: The Interplay of Distance and Conformational Effects

C Schubert, M Wielopolski, LH Mewes…

Index: Schubert, Christina; Wielopolski, Mateusz; Mewes, Lars-Hendrik; De Miguel Rojas, Gustavo; Van Der Pol, Cornelia; Moss, Kathryn C.; Bryce, Martin R.; Moser, Jacques E.; Clark, Timothy; Guldi, Dirk M. Chemistry - A European Journal, 2013 , vol. 19, # 23 p. 7575 - 7586

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Citation Number: 13

Abstract

Abstract A new series of donor–bridge–acceptor (D–B–A) compounds consisting of π- conjugated oligofluorene (oFL) bridges between a ferrocene (Fc) electron-donor and a fullerene (C 60) electron-acceptor have been synthesized. In addition to varying the length of the bridge (ie, mono-and bi-fluorene derivatives), four different ways of linking ferrocene to the bridge have been examined. The Fc moiety is linked to oFL: 1) directly without any ...