Efficient Synthesis of Cyclopropane??Fused Heterocycles with Bromoethylsulfonium Salt

SP Fritz, JV Matlock, EM McGarrigle…

Index: Fritz, Sven P.; Matlock, Johnathan V.; McGarrigle, Eoghan M.; Aggarwal, Varinder K. Chemistry - A European Journal, 2013 , vol. 19, # 33 p. 10827 - 10831

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Citation Number: 14

Abstract

The 3-azabicycloACHTUNGTRENNUNG [3.1. 0] hexane is a common motif in natural products.[1–6] Furthermore this rigid framework represents a privileged class of pharmacologically active compounds, often showing enhanced binding affinities with their targets (Figure 1).[7] These bicycles also represent conformationally restricted analogues of piperidines (eg trovafloxacin).[8] When substituted with a carboxylic acid moiety, they ...

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