Journal of the American Chemical Society

Covalent heterogenization of a discrete Mn (II) bis-phen complex by a metal-template/metal-exchange method: An epoxidation catalyst with enhanced reactivity

TJ Terry, TDP Stack

Index: Terry, Tracy J.; Daniel; Stack Journal of the American Chemical Society, 2008 , vol. 130, # 14 p. 4945 - 4953

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Citation Number: 69

Abstract

Considerable attention has been devoted to the immobilization of discrete epoxidation catalysts onto solid supports due to the possible benefits of site isolation such as increased catalyst stability, catalyst recycling, and product separation. A synthetic metal-template/metal- exchange method to imprint a covalently attached bis-1, 10-phenanthroline coordination environment onto high-surface area, mesoporous SBA-15 silica is reported herein along ...