. ALPHA.-Fluorination of Methyl Phenyl Sulfoxide and Related Compounds by Molecular Fluorine: A Novel Method for the Introduction of Fluorine into Sulfoxides …
A TOYOTA, Y ONO, J CHIBA, T SUGIHARA…
Index: Toyota, Akemi; Ono, Yoshinori; Chiba, Jun; Sugihara, Takumichi; Kaneko, Chikara Chemical and Pharmaceutical Bulletin, 1996 , vol. 44, # 4 p. 703 - 708
Full Text: HTML
Citation Number: 26
Abstract
Direct formation of α-fluorosulfones from sulfoxides bearing α-H atoms merely by reaction with molecular fluorine (5% F 2/N 2) is reported, and a novel non-Pummerer-type mechanism is proposed for this α-fluorination reaction.
Related Articles:
A novel rapid sulfoxidation of sulfides with cyclohexylidenebishydroperoxide
[Jon Paul Selvam; Suresh; Rajesh; Chanti Babu; Suryakiran; Venkateswarlu Tetrahedron Letters, 2008 , vol. 49, # 21 p. 3463 - 3465]
[Ono, Noboru; Miyake, Hideyoshi; Kamimura, Akio; Tsukui, Nobuo; Kaji, Aritsune Tetrahedron Letters, 1982 , vol. 23, # 29 p. 2957 - 2960]