Heterogeneous Palladium??Catalyzed Synthesis of Aromatic Ethers by Solvent??Free Dehydrogenative Aromatization: Mechanism, Scope, and Limitations Under …

M Sutter, R Lafon, Y Raoul, E Métay…

Index: Sutter, Marc; Lafon, Romain; Raoul, Yann; Metay, Estelle; Lemaire, Marc European Journal of Organic Chemistry, 2013 , # 26 p. 5902 - 5916

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Citation Number: 6

Abstract

Abstract Starting from cyclohexanone derivatives and alcohols, both non-aromatic precursors, aryl ethers could be synthesized in good yields and with good selectivities in the presence of a catalytic amount of Pd/C, in one step, without added solvent, in a reaction vessel open to air. For less reactive substrates, the addition of 1-octene in a closed system under non-aerobic conditions improved the conversion. In addition, the catalyst could be ...

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