Polyhedron

Synthesis and characterization of metal complexes of N-alkyl-N-phenyl dithiocarbamates

DC Onwudiwe, PA Ajibade

Index: Onwudiwe, Damian C.; Ajibade, Peter A. Polyhedron, 2010 , vol. 29, # 5 p. 1431 - 1436

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Citation Number: 43

Abstract

Ammonium N-ethyl-N-phenyl dithiocarbamate (L1) and N-butyl-N-phenyl dithiocarbamate (L2), and their group 12 metal complexes formulated as Zn2L14, CdL12, HgL12, Zn2L24, CdL22, HgL22 have been synthesized and characterized by elemental analyses, IR, 1H and 13C NMR spectroscopy. The crystal structures of the zinc complexes (Zn2L14 and Zn2L24) are also reported. Single crystal analyses of the two complexes revealed the presence of ...