d-Orbital Resonance. II. Comparative Reactivity of Vinyldimethylsulfonium and Vinyltrimethylammonium Ions1

W von E. Doering, KC Schreiber

Index: Doering; Schreiber Journal of the American Chemical Society, 1955 , vol. 77, p. 5

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Citation Number: 62

Abstract

(13) Vinyldimethylsulfonium perchlorate has been claimed as a by-product from the reaction of ethylene chlorohydrin, dimethyl sulfide and mercuric chloride at 80'for 100 hr. but the assignment of structure rests only on an unsatisfactory analysis [RA Hofmann, IC. Hobold and F Quoos, Ann., 386, 304 (lgll)]. The preparation of bis-(4-chloroethy1)-vinylsulfonium, trivinylsulfonium and vinyl-l, ddithianesulfonium salts and their reactions by addition with ...

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