The palladium-catalyzed cross-coupling reaction of 1-alkenylboranes with allylic or benzylic bromides. Convenient syntheses of 1, 4-alkadienes and allybenzenes …
N Miyaura, T Yano, A Suzuki
Index: Miyaura, Norio; Yano, Takashi; Suzuki, Akira Tetrahedron Letters, 1980 , vol. 21, p. 2865 - 2868
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Citation Number: 79
Abstract
Abstract The reactions of allylic or benzylic bromides with 1-alkenyldisiamylboranes readily available from 1-alkynes in the presence of sodium hydroxide and catalytic amounts of tetrakis-(triphenylphosphine) palladium to give corresponding 1, 4-alkadienes or allylbenzenes in good yields.
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