Tetrahedron

Base-induced α-nitration of sulfonamides

WE Truce, LW Christensen

Index: Truce,W.E.; Christensen,L.W. Tetrahedron, 1969 , vol. 25, p. 181 - 189

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Citation Number: 9

Abstract

A general procedure has been devised for the preparation of α-nitrosulfonamides. Benzylic sulfonamides, and a wide variety of N, N-dialkylalkanesulfonamides may be converted to the corresponding nitrosulfonamides via displacement by a sulfonamide-stabilized carbanion on an alkyl nitrate.