Chemical Communications

Nickel-catalyzed generation of 2-methylhex-5-enyl ethers from allyl ethers with trimethylaluminium

T Taniguchi, K Ogasawara

Index: Taniguchi, Takahiko; Ogasawara, Kunio Chemical Communications, 1998 , # 15 p. 1531 - 1532

Full Text: HTML

Citation Number: 0

Abstract

ROCH2CH=CH2 1 MeCH=CH2 ROH + DIBAL (dppp)NiCl2 aprotic solvent 2 ... 1a (α-H) b (β-H) 2a/b: 78% (from α-H) 2a/b: 80% (from β-H) ... Nickel-catalyzed generation of 2-methylhex-5-enyl ethers from allyl ethers with trimethylaluminium ... Takahiko Taniguchi and Kunio Ogasawara*† Pharmaceutical Institute, Tohoku University, Aobayama, Sendai 980-8578, Japan ... Allyl ethers have been converted into the corresponding ...