Journal of thermal analysis and calorimetry

Linear relations of activation energy in non-isothermal kinetics

D Fatu

Index: Fatu Journal of Thermal Analysis and Calorimetry, 2001 , vol. 66, # 2 p. 549 - 555

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Citation Number: 2

Abstract

Abstract The object of this work is the quantitative explanation of linear correlation between activation energy (E), initial decomposition temperature (T i) and ionic potential (V i), observed for thermal degradation of some complexes of transitional metals. The proposed model allowed the evaluation of characteristic parameter proportional to the activation free enthalpy and also the variation of effective electrical charge (Δ Q*) of ligand, in the ...