The Hydrolysis of Trimethylethylene Bromide. Mechanism of Ketone Formation
CM Suter, HD Zook
Index: Suter; Zook Journal of the American Chemical Society, 1944 , vol. 66, p. 741
Full Text: HTML
Citation Number: 16
Abstract
It has long been known that the hydrolysis of certain olefin bromides results in the formation of carbonyl compounds. Eltekoff obtained acetaldehyde and ethylene glycol from ethylene bromide or chloride, acetone and propionaldehyde from the propylene halides, isobutyraldehyde from isobutylene bromide and methyl isopropyl ketone from trimethylethylene bromide. His procedure consisted in heating the halide with lead oxide ...
Related Articles:
[Taylor, Richard T.; Flood, Lawrence A. Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5160 - 5164]
[Murayama,E.; Sato,T. Bulletin of the Chemical Society of Japan, 1978 , vol. 51, p. 3022 - 3026]
[Beak, Peter; Carter, Linda G. Journal of Organic Chemistry, 1981 , vol. 46, # 11 p. 2363 - 2373]
Direct formation of pinacols from olefins over various titano–silicates
[Sasidharan; Wu, Peng; Tatsumi, Takashi Journal of Catalysis, 2002 , vol. 209, # 1 p. 260 - 265]
Preparation and thermolysis of some 1, 2-dioxetanes
[Kopecky,K.R. et al. Canadian Journal of Chemistry, 1975 , vol. 53, p. 1103 - 1122]