Selective Markovnikov's addition of trifluoroacetic acid to alkenes using vanadium (V) oxide
BM Choudary, PN Reddy
Index: Choudary, B. M.; Reddy, P. N. Journal of the Chemical Society, Chemical Communications, 1993 , # 4 p. 405 - 407
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Citation Number: 6
Abstract
Selective functionalization of alkenes via acetoxylation is an important organic transformation, since esters formed in the reaction provide a variety of organic derivatives by simple nucleophilic exchange. 1 Earlier attempts of acetoxylation of higher alkenes by Lewis acids proceeded with concomitant isomerization to afford an isomeric mixture of acetoxylated derivatives2-4. Montmorillonite, an acid smectite clay de- signed to obtain higher ...
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