Tetrakis (tetrabutylammonium) tetrakis [(p-cyanophenyl) trioxoarsonato] tetratriacontaoxododecamolybdate (4–)

BJS Johnson, CE Buss, VG Young…

Index: Johnson, Bret J. S.; Buss, Carrie E.; Young Jr., Victor G.; Stein, Andreas Acta Crystallographica Section C: Crystal Structure Communications, 1999 , vol. 55, # 4 p. 549 - 551

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Abstract

Abstract Crystals of the title compound,(C16H36N) 4 [(p-NC-C6H4As) 4MoI2 046] or (C16H36N) 4 [{As (C7 H4N)} 4MoI2-046], were synthesized by the reaction of p-cyano- phenylarsonic acid and sodium molybdate at low pH. With nitrile groups pointed in tetrahedral directions, these new organically modified polyoxometalate clusters are potential building blocks in coordination networks.