Reactions of phenylfluorocarbene with lithium salts. Absolute kinetics of carbenoid formation

RA Moss, H Fan, R Gurumurthy…

Index: Moss, Robert A.; Fan, Hong; Gurumurthy, Ramaswamy; Guo-Jie Ho Journal of the American Chemical Society, 1991 , vol. 113, # 4 p. 1435 - 1437

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Citation Number: 16

Abstract

RO 7 a (a) R= Alk= Me (P)(a) R= H, A1= Rz= Alk= Me (p)(b) R= En, Alk= Pent (b) R= Me, R1 Rz En, Alk= Pent (c) R= Me, R1= Pivaloyl R2= H, Alk= Pent reactivity must be taken into account. The correspondence be-tween computed and experimental values in Table l encourages the hope that PM3 data can be used routinely as a qualitatioe guide to determine how or whether torsional effects can be ex-ploited in an armed/disarmed sense. ...