Bulletin of the Chemical Society of Japan

The Dehydration Reactions of Nitroparaffins and Aldoximes

T Mukaiyama, T Hata

Index: Mukaiyama,T.; Hata,T. Bulletin of the Chemical Society of Japan, 1960 , vol. 33, p. 1382 - 1386

Full Text: HTML

Citation Number: 8

Abstract

This reaction proceeds to the formation of disubstituted urea and furoxane through intermediates or amine and nitrile oxide which are formed by-the decomposition of the addition compound of isocyanate and aci-nitroparaffin with spontaneous evolution of carbon dioxide. The reaction of the amine with isocyanate yields di-substituted urea and furoxane is formed by the dimerization of nitrile oxide. Nitrite oxide, one of the two intermediates, was ...

Related Articles:

Halogenation of vinyl ketoximes. Synthesis of isoxazoles and preparation and silver ion??promoted reactions of 4??halo??2??isoxazolines

[Hansen, John F.; Kim, Yong In; McCrotty, Stephen E.; Strong, Scott A.; Zimmer, Douglas E. Journal of Heterocyclic Chemistry, 1980 , vol. 17, p. 475 - 479]

Natural products to drugs: natural product derived compounds in clinical trials

[Kidwai; Sapra Organic Preparations and Procedures International, 2001 , vol. 33, # 4 p. 381 - 386]

Stereospecific approach to α, β-disubstituted nitroalkenes via coupling of α-bromonitroalkenes with boronic acids and terminal acetylenes

[Ganesh, Madhu; Namboothiri, Irishi N.N. Tetrahedron, 2007 , vol. 63, # 48 p. 11973 - 11983]

Unsymmetrical connective olefination by kornblum nitro-synthesis: applications in phytuberin chemistry

[Crombie, Leslie; Roughley, Brian S. Tetrahedron, 1986 , vol. 42, # 12 p. 3147 - 3156]

Unsymmetrical connective olefination by kornblum nitro-synthesis: applications in phytuberin chemistry

[Crombie, Leslie; Roughley, Brian S. Tetrahedron, 1986 , vol. 42, # 12 p. 3147 - 3156]

More Articles...