Nucleophilic Displacement Reactions of Polyhalogenated Cyclopentadienes and Cyclopentenes. I

ET McBee, DL Crain, RD Crain…

Index: McBee,E.T. et al. Journal of the American Chemical Society, 1962 , vol. 84, p. 3557 - 3561

Full Text: HTML

Citation Number: 33

Abstract

The reaction of hesachlorocyclopentadiene with methanolic base has been studied. The bimolecular reaction, first order both in halide and in base, led to the formation of 1, 2, 3, 4- tetrachloro-5, 6-dimethoxycyclopentadiene exclusively. monomethoxy derivative was obtained. Further reaction with base yielded 1, 2, 3-trichloro-4, 5, 5-trimethoxycyclopenta- diene which, upon isolation and continued exposure to base, underwent two ...

Related Articles:

Synthetic approaches to chlorinated 5-hydroxy-5-methyl-2-furanones

[Franzen, Robert; Kronberg, Leif Tetrahedron, 1993 , vol. 49, # 47 p. 10945 - 10958]

Untersuchungen über 1.2??Dihalogen??cyclopenten??(1)??dione??(3.5)

[Roedig,A.; Ziegler,H. Chemische Berichte, 1961 , vol. 94, p. 1800 - 1813]

Untersuchungen über 1.2??Dihalogen??cyclopenten??(1)??dione??(3.5)

[Roedig,A.; Ziegler,H. Chemische Berichte, 1961 , vol. 94, p. 1800 - 1813]

Umlagerungen vinyloger Carbonsäurechloride, VII1) Die cis??trans??Isomerisierung als Konkurrenzreaktion der 1.5??Pentadien??Sauerstoff??Verschiebung und der Pyron …

[Roedig; Maerkl Justus Liebigs Annalen der Chemie, 1960 , vol. 636, p. 1,13]

… vinyloger Carbonsäurechloride, IV. Umlagerung von 1.1. 2??Trichlor??3.4??dibrom??pentadien??(1.3)??al??(5) und von 1.2. 3.4??Tetrachlor??1??brom??pentadien??(1.3)??al??(5)

[Roedig,A. et al. Justus Liebigs Annalen der Chemie, 1966 , vol. 692, p. 83 - 93]

More Articles...