Reaction of nitroso chlorides with sodium borohydride: Selective anti-Markovnikov hydration of a diene

KH Bell

Index: Bell,K.H. Australian Journal of Chemistry, 1971 , vol. 24, p. 1089 - 1091

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Abstract

SHORT COMMUNICATIONS 1091 and for 20 min afterwards, before being dropped to-50'. Tho white precipitate was quickly filtered off, washed with a little cold trichloroethylene, and dried under vacuum (6.92 g, 21%; mp 88-80", lit. 9 95-97"). The nmr spectrum showed a very complex multiplet extending over 6 5.36-6.0 (CH-NO; cf. cis nitroso chloride of cyclohexene, multiplet 6 5.2; trans nitroso chloride of cyclohexene, multiplet 6 5.499) indicating the ...