Enamine Chemistry. VIII. 1 Reactions with Miscellaneous Carbonyl and Active Hydrogen Compounds2

KC Brannock, RD Burpitt, HE Davis…

Index: Brannock,K.C. et al. Journal of Organic Chemistry, 1964 , vol. 29, p. 2579 - 2582

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Citation Number: 19

Abstract

Reaction with Diethyl Malonate.-Diethyl malonate is reactive at the methylene position rather than at a carbonyl group. When this ester was heated with N, N-diniethylisobutenylamine, dimethylamine was evolved and the product obtained on distillation appeared to he mainly diethyl isobutylidenemalonate (9). h second component, shown to be present by vapor phase chromatography, was apparently diethyl isobutenylmalonate (10) since ...