Ruthenium (II)-catalyzed reactions of 1, 4-epiperoxides
…, H Ohtake, Y Kameya, N Hamanaka…
Index: Suzuki, Masaaki; Ohtake, Hiroaki; Kameya, Yoshimi; Hamanaka, Nobuyuki; Noyori, Ryoji Journal of Organic Chemistry, 1989 , vol. 54, # 22 p. 5292 - 5302
Full Text: HTML
Citation Number: 73
Abstract
The behavior of 1, 4-epiperoxides in the presence of transition-metal complexes is highly dependent on the structures of the substrates and the nature of the metal catalysts. Reaction of saturated epiperoxides such as 1, 3-epiperoxycyclopentane, 1, 4-epiperoxycyclohexane, or dihydroascaridole catalyzed by RUC~~(PP~~)~ in dichloromethane gives a mixture of products arising from fragmentation, rearrangement, reduction, disproportionation, etc. ...
Related Articles:
Formation of dicarbonyl compounds in the flash vacuum pyrolysis of saturated bicyclic peroxides
[Bloodworth, A. J.; Baker, David S.; Eggelte, Henny J. Journal of the Chemical Society, Chemical Communications, 1982 , # 18 p. 1034 - 1036]
[Yamane, Takehiro; Makino, Kohei; Umezawa, Naoki; Kato, Nobuki; Higuchi, Tsunehiko Angewandte Chemie - International Edition, 2008 , vol. 47, # 34 p. 6438 - 6440]
Ruthenium (II) catalyzed reaction of 1, 4-epiperoxides
[Suzuki, M.; Noyori, R.; Hamanaka, N. Journal of the American Chemical Society, 1982 , vol. 104, # 7 p. 2024 - 2025]
[Yamane, Takehiro; Makino, Kohei; Umezawa, Naoki; Kato, Nobuki; Higuchi, Tsunehiko Angewandte Chemie - International Edition, 2008 , vol. 47, # 34 p. 6438 - 6440]
CoTPP-catalyzed reaction of saturated bicyclic endoperoxides
[Balci, Metin; Akbulut, Nihat Tetrahedron, 1985 , vol. 41, # 7 p. 1315 - 1322]