Preparation of the nitryl salts ON (Cl) F+ AsF6-, ON (CF3) F+ AsF6-, and HON (CH2) CF3+ SbF6-and crystal structure of HON (CH2) CF3+ AsF6
R Minkwitz, D Bernstein, H Preut, P Sartori
Index: Minkwitz, Rolf; Bernstein, Dirk; Preut, Hans; Sartori, Peter Inorganic Chemistry, 1991 , vol. 30, p. 2157 - 2161
Full Text: HTML
Citation Number: 16
Abstract
The oN (cI) F+ AsF6-and ON (CFJF+ AsF; salts are prepared by oxidative fluorination of ONCI and ONCF3 with N2F+ AsF (. Methylation of ONCF, with CH3F and AsFJ gives ON (cH3) CF3+ AsF6-, which in the solid state exists as the enol tautomer hydroxylimmonium salt HON (CH2) CF3+ AsF6-, triclinic, of space group PT with a= 5.063 (I) A, b= 7.757 (3) A, c= 10.429 (2) A, CY= 86.75 (2) O, fl= 89.34 (2) O, and y= 74.12 (2)". The framework of the ...
Related Articles:
Preparation, Properties and Reactions of Bismuth Pentafluoride1
[Fisher, J.; Rudzitis, E. Journal of the American Chemical Society, 1959 , vol. 81, p. 6375 - 6377]
[Hinds, K.; Holloway, J. H.; Legon, A. C. Chemical Physics Letters, 1995 , vol. 242, p. 407 - 414]
The Chemical Properties of Dioxygen Difluoride
[Streng, A. Journal of the American Chemical Society, 1963 , vol. 85, p. 1380 - 1385]
Preparation, Properties and Reactions of Bismuth Pentafluoride1
[Fisher, J.; Rudzitis, E. Journal of the American Chemical Society, 1959 , vol. 81, p. 6375 - 6377]
Millimeter wave measurements of the rotational spectra of ClF, BrF, BrCl, ICl, and IBr
[Willis, Robert E.; Clark, William W. Journal of Chemical Physics, 1980 , vol. 72, # 9 p. 4946 - 4950]