Reactions of 2-(α-Haloalkyl) thiiranes with nucleophilic reagents: V. Reactions of 2-(α-Chloroalkyl) thiiranes with organolithium compounds
AA Tomashevskii, VV Sokolov, AA Potekhin
Index: Tomashevskii; Sokolov; Potekhin Russian Journal of Organic Chemistry, 2010 , vol. 46, # 12 p. 1822 - 1825
Full Text: HTML
Citation Number: 0
Abstract
Abstract 2-(α-Haloalkyl) thiiranes reacted with methyl-, butyl-, and phenyllithium to give the corresponding allyl sulfides. The reactions of diastereoisomeric erythro-and threo-2-(1- chloroethyl) thiiranes with phenyllithium were stereospecific, and they afforded (E)-and (Z)-1- phenylsulfanylbut-2-enes, respectively. 3-Chloromethyl-2, 2-dimethylthiirane and phenyllithium gave rise to a mixture of 3-methyl-3-phenylsulfanylbut-1-ene and 3-methyl-1 ...
Related Articles:
Synthesis and antioxidant activity of 1-amino-4-phenyl-2-butanethiols
[Guseinova; Alieva; Rzaeva; Magerramov; Aliev; Farzaliev; Allakhverdiev Russian Journal of Applied Chemistry, 2009 , vol. 82, # 9 p. 1587 - 1591]
Synthesis and structure of some aryl-substituted thiiranes
[Allakhverdiev; Mustafaev; Farzaliev Russian Journal of Organic Chemistry, 2002 , vol. 38, # 11 p. 1620 - 1623]
On the conformational preferences of the dehydrochlorination of α-chlorosulfoxides
[Schwan, Adrian L.; Roche, Michael R.; Gallagher, John F.; Ferguson, George Canadian Journal of Chemistry, 1994 , vol. 72, # 2 p. 312 - 324]
Synthesis and antioxidant activity of 1-amino-4-phenyl-2-butanethiols
[Guseinova; Alieva; Rzaeva; Magerramov; Aliev; Farzaliev; Allakhverdiev Russian Journal of Applied Chemistry, 2009 , vol. 82, # 9 p. 1587 - 1591]