Synthesis and biological evaluation of bilobol and adipostatin A

A Tanaka, Y Arai, SN Kim, J Ham…

Index: Tanaka, Ayano; Arai, Yasuhiro; Kim, Su-Nam; Ham, Jungyeob; Usuki, Toyonobu Journal of Asian Natural Products Research, 2011 , vol. 13, # 4 p. 290 - 296

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Citation Number: 12

Abstract

Concise total synthesis of bilobol 5-pentadecenylresorcinol (1), isolated from Gingko biloba fruits, has been achieved in 10 steps with 51% overall yield from 3, 5-dihydroxybenzoic acid (3). Adipostatin A (2), isolated from the fruits as well as from Streptomyces cyaneus 2299- SV1, has also been synthesized in two steps from methylated bilobol (10). The structure– activity relationship study of synthetic products was described by means of cytotoxic assay ...

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