Tetracyclohexylsilane: The resolution of an enigma

L Spialter, GR Buell, CW Harris, JD Austin

Index: Spialter,L. et al. Journal of Organometallic Chemistry, 1967 , vol. 8, p. 69 - 77

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Citation Number: 3

Abstract

Abstract The conflicting experimental data and subsequent rationalizations in the literature on tetracyclohexylsilane are critically examined. It is established that the authentic compound, obtained by hydrogenation of tetraphenylsilane, can be synthesized by organolithium condensation, although a prior report mistakenly identified an impurity-caused product, tricyclohexyl (cyclohexyloxy) silane, as such. Studies on cyclohexyllithium and ...