Competitive singlet-singlet energy transfer and electron transfer activation of aryl azides: application to photo-cross-linking experiments

…, GB Schuster, O Buchardt, PE Nielsen

Index: Shields, Charles J.; Falvey, Daniel E.; Schuster, Gary B.; Buchardt, Ole; Nielsen, Peter E. Journal of Organic Chemistry, 1988 , vol. 53, # 15 p. 3501 - 3507

Full Text: HTML

Citation Number: 35

Abstract

Conclusion A complete set of a,@-unsaturated carbonyl compounds has been examined, and the results allow the following conclusions: a good correlation of AHfo (MH+) with the logarithm of the number of atoms is observed, pointing to protonation on the oxygen of the carbonyl group; the effect of methyl substitution upon gas-phase basicities is to increase significantly the latter when situated on position C (1) or C (3); the gas-phase basicity of an ...