Synthesis

Development of Novel Reactions Using Hypervalent Iodine (III) Reagents: Total Synthesis of Sulfur-Containing Pyrroloiminoquinone Marine Product,(±)- …

Y Kita, M Egi, T Takada, H Tohma

Index: Kita, Yasuyuki; Egi, Masahiro; Takada, Takeshi; Tohma, Hirofumi Synthesis, 1999 , # 5 p. 885 - 897

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Citation Number: 49

Abstract

Abstract: Novel and efficient intramolecular nucleophilic substitution reactions of phenol ethers using activated hypervalent iodine species have been developed and their application to the total synthesis of strongly cytotoxic makaluvamine F (1), a member of sulfur- containing pyrroloiminoquinone marine products, is described. Key words: hypervalent iodine reagents, phenol ethers, cation radical, makaluvamine F, N, S-acetal

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