Journal of fluorine chemistry

Etude de la reaction de l'acide methacrylique avec un epoxyde fluore. Catalyse par le sel de potassium de l'acide.

C Guery, M Viguier, A Commeyras

Index: Guery, C.; Viguier, M.; Commeyras, A. Journal of Fluorine Chemistry, 1987 , vol. 35, p. 497 - 512

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Citation Number: 3

Abstract

Abstract Reaction of methacrylic acid with 1 F-alkyl 2, 3-epoxy propane (EC 6) is a synthetic route to acrylic monomers carrying the perfluorinated group. Reaction in a melt is catalysed by the potassium salt of the acid. Kinetic studies have been carried out in stoichiometric and non stoichiometric conditions according to salt concentration. A non integral global order shows the complexity of the reaction.