Catalytic Asymmetric Alkylation Reactions for the Construction of Protected Ethylene??Amino and Propylene??Amino Motifs Attached to Quaternary Stereocentres
…, DM Barber, AF Kyle, DJ Dixon
Index: Moss, Thomas A.; Barber, David M.; Kyle, Andrew F.; Dixon, Darren J. Chemistry - A European Journal, 2013 , vol. 19, # 9 p. 3071 - 3081
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Citation Number: 15
Abstract
Abstract An efficient catalytic and stereoselective method for the direct construction of protected ethylene-amino and propylene-amino scaffolds attached to quaternary stereocentres is reported. Preliminary investigations revealed a mild base catalysed nucleophilic ring opening of N-sulfonyl aziridines using the commercially available phosphazene base 2-tert-butylimino-2-diethylamino-1, 3-dimethyl-perhydro-1, 3, 2- ...
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