Phosphine-free conversion of alcohols into alkyl thiocyanates using trichloroisocyanuric acid/NH 4 SCN
R Azadi, B Mokhtari, MA Makaremi
Index: Azadi, Roya; Mokhtari, Babak; Makaremi, Mohamad-Ali Chinese Chemical Letters, 2012 , vol. 23, # 1 p. 77 - 80
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Citation Number: 4
Abstract
Trichloroisocyanuric acid [1,3,5-trichoro-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione or TCCA] belongs to the large group of N-chloroimides and amides which is a subgroup of the more general N-chloroamines [1]. This reagent has been previously applied for organic transformation include chlorination of alkenes [2], ketones [3], sulfides [4], cyclic ethers [5], N-heterocycles [6], and alcohols [7]; conversion of carboxylic acids to amides or esters [8]; dehydrogenation of amines [9]; ...
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