Catalytic asymmetric addition of thiols to nitrosoalkenes leading to chiral non-racemic α-sulfenyl ketones
JM Hatcher, MC Kohler, DM Coltart
Index: Reese, Colin B.; Sanders, H. Paul Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , # 11 p. 2719 - 2724
Full Text: HTML
Citation Number: 13
Abstract
... Select a Journal or Book ... racemic 18 was prepared and combined with catalyst 14 in CH 2 Cl 2 . The product composition was analyzed after 1 h and showed a 50 ... figure Scheme 2. (a) Determination of Absolute Stereochemistry; (b) Proposed Nitrosoalkenes Intermediates. ...
Related Articles:
[Craig, Donald; Daniels, Kevin; MacKenzie, A. Roderick Tetrahedron, 1993 , vol. 49, # 48 p. 11263 - 11304]
Reactivity of α-halogenated aldehydes towards thiolates: synthesis of α-sulfenylated aldehydes
[Verhe, R.; Kimpe, N. De; Buyck, L. De; Schamp, N. Synthesis, 1984 , # 1 p. 46 - 49]
[Craig, Donald; Daniels, Kevin; MacKenzie, A. Roderick Tetrahedron, 1993 , vol. 49, # 48 p. 11263 - 11304]
[Faull, Alan W.; Brewster, Andrew G.; Brown, George R.; Smithers, Michael J.; Jackson, Ruth Journal of Medicinal Chemistry, 1995 , vol. 38, # 4 p. 686 - 694]
Recent advances in asymmetric synthesis
[Groenewegen,P. et al. Tetrahedron Letters, 1979 , p. 2817 - 2820]