Novel photoreactions of 2-aza-1, 4-dienes in the triplet excited state and via radical-cation intermediates. 2-Aza-di-π-methane rearrangements yielding …

…, AR Agarrabeitia, M Martin-Fontecha…

Index: Armesto, Diego; Caballero, Olga; Ortiz, Maria J.; Agarrabeitia, Antonia R.; Martin-Fontecha, Mar; Torres, M. Rosario Journal of Organic Chemistry, 2003 , vol. 68, # 17 p. 6661 - 6671

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Citation Number: 17

Abstract

Triplet-sensitized irradiation of 2-aza-1, 4-dienes affords N-cyclopropylimines via 2-aza-di-π- methane (2-ADPM) rearrangement pathways. In the case of the pentaphenyl-substituted azadiene 1, irradiation leads to formation of cyclopropylimine 2 as well as N-vinylaziridine 3. The transformations represent the first examples of di-π-methane rearrangement reactions that yield three-membered heterocyclic products. SET-sensitized irradiation of 2-aza-1, 4- ...

Rapid Ti (Oi-Pr) 4 facilitated synthesis of α, α, α-trisubstituted primary amines by the addition of Grignard reagents to nitriles under microwave heating conditions

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Bis tertiary amide inhibitors of the HIV-1 protease generated via protein structure-based iterative design

[Melnick, Michael; Reich, Siegfried H.; Lewis, Kathy K.; Mitchell Jr., Lennert J.; Nguyen, Dzuy; Trippe, Anthony J.; Dawson, Heather; Davies II, Jay F.; Appelt, Krzysztof; Wu, Bor-Wen; Musick, Linda; Gehlhaar, Dan K.; Webber, Stephanie; Shetty, Bhasker; Kosa, Maha; Kahil, Deborah; Andrada, Dominic Journal of Medicinal Chemistry, 1996 , vol. 39, # 14 p. 2795 - 2811]

Bis tertiary amide inhibitors of the HIV-1 protease generated via protein structure-based iterative design

Organocerium reactions of benzamides and thiobenzamides: A direct synthesis of tertiary carbinamines

[Calderwood, David J.; Davies, Roy V.; Rafferty, Paul; Twigger, Helen L.; Whelan, Helen M. Tetrahedron Letters, 1997 , vol. 38, # 7 p. 1241 - 1244]

Novel photoreactions of 2-aza-1, 4-dienes in the triplet excited state and via radical-cation intermediates. 2-Aza-di-π-methane rearrangements yielding …

Abstract

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