The Journal of Organic Chemistry

Micellar effects on the monohalogenation of n-pentyl phenyl ether

DA Jaeger, RE Robertson

Index: Jaeger,D.A.; Robertson,R.E. Journal of Organic Chemistry, 1977 , vol. 42, p. 3298 - 3301

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Citation Number: 28

Abstract

Preparation of 3. A 303-mg sample of phosphonic acid la7 in 5.8 mL of TFA was heated to'75" C for 5 days, after which'H NMR indicated no starting material and-85% pure 3.5 The burgandy colored solution was rotary evaporated, dissolved in 5 mL of benzene, then rotary evaporated again. The dark semisolid residue was recrystsllized four times from minimum benzene to give 137 mg (42%) of colorless 3, mp 167-168 OC. Its lH NMR spectrum is ...