Chemistry Letters

Metathesis of oleyl chloride

R Nakamura, E Echigoya

Index: Nakamura,R.; Echigoya,E. Chemistry Letters, 1977 , p. 1227 - 1230

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Citation Number: 14

Abstract

The metathesis of oleyl chloride (1-chloro-cis-9-octadecene) with an alkene such as 1- hexene, 5-decence, 2-butene, etc., and the disproportionation of oleyl chloride were found to be effectively catalyzed by a modified or unmodified Re 2 O 7–Al 2 O 3 catalyst at ambient temperature. The activity of the modified catalyst with Me x O y such as V 2 O 5, MoO 3, WO 3, GeO 2, Re 2 O 7–Me x O y–Al 2 O 3, was very high even at low Re contents. This ...