Organic letters

Nickel (0) triethyl phosphite complex-catalyzed allylic substitution with retention of regio-and stereochemistry

Y Yatsumonji, Y Ishida, A Tsubouchi, T Takeda

Index: Yatsumonji, Yasutaka; Ishida, Yusuke; Tsubouchi, Akira; Takeda, Takeshi Organic Letters, 2007 , vol. 9, # 22 p. 4603 - 4606

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Citation Number: 53

Abstract

Nickel (0) triethyl phosphite complex-promoted reaction of allylic acetates with thiols produced allylic sulfides with retention of configuration without allylic rearrangement. A similar reaction of allylic acetates with alcohols and phenols also proceeded with retention of regio-and stereochemistry.

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