Action of di-tert-butylperoxide or of. gamma.-radiations on 2, 3-dimethylbutane. Identification of the C12 hydrocarbons
PJL Gouverneur
Index: Gouverneur,P.J.L. Journal of Organic Chemistry, 1977 , vol. 42, p. 3051 - 3057
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Citation Number: 6
Abstract
The reaction between 2, 3-dimethylbutane and di-tert-butyl peroxide might lead in principle to 21 saturated and unsaturated products. Capillary GLC reveals six major compounds which have been isolated by fractional preparative GLC; and whose structure has been far the first time unambiguously determined by spectroscopy ('H NMR, l3C NMR, mass), independent synthesis, hydrogenation of reaction mixtures, and chromatographic ...
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