Rhodium-catalysed addition of organotrialkoxysilanes to α-substituted acrylic esters
JD Hargrave, J Herbert, G Bish, CG Frost
Index: Hargrave, Jonathan D.; Herbert, Jennifer; Bish, Gerwyn; Frost, Christopher G. Organic and Biomolecular Chemistry, 2006 , vol. 4, # 17 p. 3235 - 3241
Full Text: HTML
Citation Number: 29
Abstract
The cationic rhodium complex [Rh (cod) 2][BF4] effectively catalyses the 1, 4-addition of organotrialkoxysilanes to α-substituted acrylic esters. The reactions are promoted by heating in an oil-bath or more conveniently in a microwave reactor allowing rapid access to a useful range of functionalised products including 2-alkyl succinates and α-amino acid derivatives.
Related Articles:
[Le Notre, Jerome; Van Mele, David; Frost, Christopher G. Advanced Synthesis and Catalysis, 2007 , vol. 349, # 3 p. 432 - 440]
[Kawano, Hiroyuki; Ikariya, Takao; Ishii, Youichi; Saburi, Masahiko; Yoshikawa, Sadao; et al. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 1571 - 1575]
[Dai, Mingji; Wang, Cuihua; Dong, Guangbin; Xiang, Jing; Luo, Tuoping; Liang, Bo; Chen, Jiahua; Yang, Zhen European Journal of Organic Chemistry, 2003 , # 22 p. 4346 - 4348]
[Wadsworth, Kelly J.; Wood, Frances K.; Chapman, Christopher J.; Frost, Christopher G. Synlett, 2004 , # 11 p. 2022 - 2024]
Decatungstate As Photoredox Catalyst: Benzylation of Electron-Poor Olefins
[Montanaro, Sara; Ravelli, Davide; Merli, Daniele; Fagnoni, Maurizio; Albini, Angelo Organic Letters, 2012 , vol. 14, # 16 p. 4218 - 4221]