Allylstannanes. Synthesis, structure, and reactions of 2-methylene-1, 3-propanediylbis [trimethylstannane] and-[triphenylstannane]

S Chandrasekhar, S Latour, JD Wuest…

Index: Chandrasekhar, Sosale; Latour, Stephan; Wuest, James D.; Zacharie, Boulos Journal of Organic Chemistry, 1983 , vol. 48, # 21 p. 3810 - 3813

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Citation Number: 16

Abstract

Method. Triethylamine (0.04 mol) was added to a solution of (phenylsulfiny1) alkenes (0.01 mol) and a-chlorobenzaldehyde phenylhydrazone (0.01 mol) in benzene (100 mL), and the mixture was refluxed for 20 h (see Table I). The solvent was evaporated off, and the residue was chromatographed on silica gel. Elution with benzene gave the products listed in Table I.