Rearrangement Strategy for the Synthesis of 2-Aminoanilines
A Porzelle, MD Woodrow, NCO Tomkinson
Index: Porzelle, Achim; Woodrow, Michael D.; Tomkinson, Nicholas C.O. Organic Letters, 2010 , vol. 12, # 7 p. 1492 - 1495
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Citation Number: 10
Abstract
Treatment of N-aryl hydroxylamines with trichloroacetonitrile in the presence of imidazole provides a simple and effective method for the preparation of synthetically versatile 2- aminoanilines. Reactions proceed in DMF at 40° C, providing the products in up to 86% isolated yield.
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