The design and synthesis of novel IBiox N-heterocyclic carbene ligands derived from substituted amino-indanols
JN Levy, CM Latham, L Roisin, N Kandziora…
Index: Levy, Jean-Noel; Latham, Christopher M.; Roisin, Loic; Kandziora, Nadine; Fruscia, Paolo Di; White, Andrew J. P.; Woodward, Simon; Fuchter, Matthew J. Organic and Biomolecular Chemistry, 2012 , vol. 10, # 3 p. 512 - 515
Full Text: HTML
Citation Number: 13
Abstract
A synthetic route towards a number of novel IBiox N-heterocyclic carbene (NHC) ligands has been developed. The resulting ligands have restricted flexibility and high steric demand. Preliminary studies have shown these ligands to give high levels of asymmetric induction in the copper-free allylic alkylation of cinnamyl bromide.
Related Articles:
Perhydroindanone derivatives. II. Stability relationships
[House,H.O.; Rasmusson,G.H. Journal of Organic Chemistry, 1963 , vol. 28, p. 31 - 34]
Perhydroindanone derivatives. II. Stability relationships
[House,H.O.; Rasmusson,G.H. Journal of Organic Chemistry, 1963 , vol. 28, p. 31 - 34]
[Bednarek; Zhu; Bally; Filipiak; Marcinek; Gebicki Journal of the American Chemical Society, 2001 , vol. 123, # 10 p. 2377 - 2387]
[Kobayashi, Toyoharu; Tanaka, Katsunori; Miwa, Junichi; Katsumura, Shigeo Tetrahedron Asymmetry, 2004 , vol. 15, # 2 p. 185 - 188]
An NMR investigation of the Mills-Nixon effect
[Collins, Michael J.; Gready, Jill E.; Sternhell, Sever; Tansey, Charles W. Australian Journal of Chemistry, 1990 , vol. 43, p. 1547 - 1557]