Bulletin of the Chemical Society of Japan

Synthesis and Physical Properties of Normal Higher Alcohols. I. Synthesis of Normal Higher Primary Alcohols of Odd Carbon Numbers from Undecanol to …

A Watanabe

Index: Watanabe Bulletin of the Chemical Society of Japan, 1959 , vol. 32, p. 1295,1297

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Citation Number: 8

Abstract

Method C which was used for the synthesis of tricosanol C23H47OH and-pentacosanol C25H51OH is analogous to that of Bowman's ketone synthesis->. Ethyl n-hexane-1, 1, 6- tricarboxylate(II) which served as the starting material was prepared from ethyl malonate and ethyl bromocaproate which was obtained from cyclohexanone by the method of Browns). Benzyl n-hexane-1, 1, 6-tricarboxylate derived from the ethyl ester by transesterifi-cation ...